In most atoms, electrons occur in pairs. Each electron in a pair spins in the opposite direction. So when electrons are paired together, their opposite spins cause there magnetic fields to cancel each other. Therefore, no net magnetic field exists. Alternately, materials with some unpaired electrons will have a net magnetic field and will react more to an external field. Most materials can be classified as ferromagnetic, diamagnetic or paramagnetic.

Diamagnetic metals have a very weak and negative susceptibility to magnetic fields. Diamagnetic materials are slightly repelled by a magnetic field and the material does not retain the magnetic properties when the external field is removed. Diamagnetic materials are solids with all paired electron and, therefore, no permanent net magnetic moment per atom. Diamagnetic properties arise from the realignment of the electron orbits under the influence of an external magnetic field. Most elements in the periodic table, including copper, silver, and gold, are diamagnetic.

Paramagnetic metals have a small and positive susceptibility to magnetic fields. These materials are slightly attracted by a magnetic field and the material does not retain the magnetic properties when the external field is removed. Paramagnetic properties are due to the presence of some unpaired electrons and from the realignment of the electron orbits caused by the external magnetic field. Paramagnetic materials include magnesium, molybdenum, lithium, and tantalum.

Ferromagnetic materials have a large and positive susceptibility to an external magnetic field. They exhibit a strong attraction to magnetic fields and are able to retain their magnetic properties after the external field has been removed. Ferromagnetic materials have some unpaired electrons so their atoms have a net magnetic moment. They get their strong magnetic properties due to the presence of magnetic domains. In these domains, large numbers of atoms moments (10¹² to 10¹⁵) are aligned parallel so that the magnetic force within the domain is strong. When a ferromagnetic material is in the unmagnitized state, the domains are nearly randomly organized and the net magnetic field for the part as a whole is zero. When a magnetizing force is applied, the domains become aligned to produce a strong magnetic field within the part. Iron, nickel, and cobalt are examples of ferromagnetic materials. Components with these materials are commonly inspected using the magnetic particle method.